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Synthesis, spectroscopy, x-ray crystallography, and dft studies of dichlorobis [1-(allyl)-1h-imidazole-κn3] copper(II)
(Pleiades Publishing, 15.04.2019)Abstract—The synthesis and characterization of Cu(II) complex bearing N-allylimidazole as ligand have been described and studied by elemental analyses and spectroscopic (FT-IR, UV–Vis) measurements. Molecular structure of ... -
Palladium - carbene catalyzed direct arylation of five - membered heteroaromatics
(Elsevier, 03.01.2020)Due to the industrial importance of bi(hetero)arenes, the synthesis of these compounds by homogeneous Pd-catalyzed direct arylation is an important research topic in modern organic chemistry. In this study, PEPPSI-type, ... -
The efects of serum levels, and alterations in the genes of binding protein and receptor of vitamin D on gastric cancer
(Springer Nature, 2019)Due to many biological cell functions of vitamin D including regulation of cell survival, proliferation and differentiation, the metabolism of itself gains importance in the development of several types of cancer. This ... -
Well‐defined PEPPSI‐themed palladium–NHC complexes: synthesis, and catalytic application in the direct arylation of heteroarenes
(John Wiley & Sons, Inc., 2019-09-20)In this study, a series of benzimidazolium salts were synthesized as unsymmetrical N‐heterocyclic carbene (NHC) precursors. Benzimidazolium salts were used for synthesis of the PEPPSI (pyridine enhanced precatalyst preparation ... -
EPR study of Cu2+ ion doped orotato (nicotinamid) cobalt (II) single crystal
(Pergamon-Elsevier Science Ltd., 2016)We have studied the Cu2+ ion doped orotato(nicotinamid)cobalt(II) complex by using EPR spectroscopy and X-ray diffraction. The single crystal is triclinic with the space group P (1) over bar. The unit cell dimensions of ... -
EPR study of gamma irradiated DL-methionine sulfone single crystals
(Elsevier Science Bv, 2015)Electron paramagnetic resonance (EPR) study of gamma irradiated dl-2-amino-4-(Methylsulfonyl) butyric acid (dl-methionine sulfone, hereafter dl-ABA) single crystals and powder was performed at room temperature. It has been ... -
Theoretical and experimental EPR and optical studies of [Cu(1-Meim)(4)(H2O)] center dot 2Cl center dot H2O single crystals
(Amer Inst Physics, 2016)[Cu(1-meim)(4)(H2O)]center dot 2Cl center dot H2O (1-meim: 1-methylimidazole) complex has been investigated by EPR and UV techniques. EPR spectra of [Cu(1-meim)(4)(H2O)]center dot 2Cl center dot H2O single crystal have ... -
Characterizing the paramagnetic behavior of Cu2+ doped nickel(II) dipicolinato by using theoretical and experimental EPR and UV-vis studies
(Elsevier Science Bv., 2016)In this study, the paramagnetism in bis(hydrogeno pyridine-2,6-dicarboxylato) nickel(II) trihydrate, [Ni(Hdpc)(2)]center dot 3H(2)O, has been investigated after doping the sample with Cu2+ ions. The g and hyperfine parameters ... -
EPR Study of [Cu(Him)4]•2Br Complex
(Institute of Physics Publishing, 2016)The single crystal of [Cu(Him)4]•2Br (Him: C3H4N2, imidazole) complex has been investigated at ambient temperature in three mutually perpendicular planes by EPR technique. The magnetic environments of [Cu(Him)4]•2Br complex ...